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Thread: JEE Main Chemistry Syllabus 2014

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    Chat JEE Main Chemistry Syllabus 2014

    SECTION: A





    PHYSICAL CHEMISTRY

    UNIT 1: SOME BASIC CONCEPTS IN CHEMISTRY

    Matter and its nature, Dalton’s atomic theory; Concept of atom, molecule, element and compound; Physical quantities and their measurements in Chemistry, precision and accuracy, significant figures, S.I. Units, dimensional analysis; Laws of chemical combination; Atomic and molecular masses, mole concept, molar mass, percentage composition, empirical and molecular formulae; Chemical equations and stoichiometry.

    JEE Main 2014 Chemistry Syllabus

    UNIT 2: STATES OF MATTER

    Classification of matter into solid, liquid and gaseous states.

    Gaseous State:

    Measurable properties of gases; Gas laws – Boyle’s law, Charle’s law, Graham’s law of diffusion, Avogadro’s law, Dalton’s law of partial pressure; Concept of Absolute scale of temperature; Ideal gas equation; Kinetic theory of gases (only postulates); Concept of average, root mean square and most probable velocities; Real gases, deviation from Ideal behaviour, compressibility factor and van der Waals equation.

    JEE Main 2014 Chemistry Syllabus

    Liquid State:

    Properties of liquids – vapour pressure, viscosity and surface tension and effect of temperature on them (qualitative treatment only).

    Solid State:

    Classification of solids: molecular, ionic, covalent and metallic solids, amorphous and crystalline solids (elementary idea); Bragg’s Law and its applications; Unit cell and lattices, packing in solids (fcc, bcc and hcp lattices), voids, calculations involving unit cell parameters, imperfection in solids; Electrical, magnetic and dielectric properties.

    JEE Main 2014 Chemistry Syllabus

    UNIT 3: ATOMIC STRUCTURE

    Thomson and Rutherford atomic models and their limitations; Nature of electromagnetic radiation, photoelectric effect; Spectrum of hydrogen atom, Bohr model of hydrogen atom – its postulates, derivation of the relations for energy of the electron and radii of the different orbits, limitations of Bohr’s model; Dual nature of matter, de-Broglie’s relationship, Heisenberg uncertainty principle.

    JEE Main 2014 Chemistry Syllabus

    Elementary ideas of quantum mechanics, quantum mechanical model of atom, its important features, ?? and ??2, concept of atomic orbitals as one electron wave functions; Variation of ?? and ??2 with r for 1s and 2s orbitals; various quantum numbers (principal, angular momentum and magnetic quantum numbers) and their significance; shapes of s, p and d – orbitals, electron spin and spin quantum number; Rules for filling electrons in orbitals – aufbau principle, Pauli’s exclusion principle and Hund’s rule, electronic configuration of elements, extra stability of half-filled and completely filled orbitals.

    UNIT 4: CHEMICAL BONDING AND MOLECULAR STRUCURE

    Kossel – Lewis approach to chemical bond formation, concept of ionic and covalent bonds.

    Ionic Bonding: Formation of ionic bonds, factors affecting the formation of ionic bonds; calculation of lattice enthalpy.



    JEE Main 2014 Chemistry Syllabus

    Covalent Bonding: Concept of electronegativity, Fajan’s rule, dipole moment; Valence Shell Electron Pair Repulsion (VSEPR) theory and shapes of simple molecules. Quantum mechanical approach to covalent bonding: Valence bond theory – Its important features, concept of hybridization involving s, p and d orbitals; Resonance.

    Molecular Orbital Theory – Its important features, LCAOs, types of molecular orbitals (bonding, antibonding), sigma and pi-bonds, molecular orbital electronic configurations of homonuclear diatomic molecules, concept of bond order, bond length and bond energy.

    JEE Main 2014 Chemistry Syllabus

    Elementary idea of metallic bonding. Hydrogen bonding and its applications.

    UNIT 5: CHEMICAL THERMODYNAMICS

    Fundamentals of thermodynamics: System and surroundings, extensive and intensive properties, state functions, types of processes.

    First law of thermodynamics – Concept of work, heat internal energy and enthalpy, heat capacity, molar heat capacity; Hess’s law of constant heat summation; Enthalpies of bond dissociation, combustion, formation, atomization, sublimation, phase transition, hydration, ionization and solution. Second law of thermodynamics; Spontaneity of processes; DS of the universe and DG of the system as criteria for spontaneity, Dgo (Standard Gibbs energy change) and equilibrium constant.

    JEE Main 2014 Chemistry Syllabus

    UNIT 6: SOLUTIONS

    Different methods for expressing concentration of solution – molality, molarity, mole fraction, percentage (by volume and mass both), vapour pressure of solutions and Raoult’s Law – Ideal and non-ideal solutions, vapour pressure – composition, plots for ideal and non-ideal solutions; Colligative properties of dilute solutions – relative lowering of vapour pressure, depression of freezing point, elevation of boiling point and osmotic pressure; Determination of molecular mass using colligative properties; Abnormal value of molar mass, van’t Hoff factor and its significance.

    JEE Main 2014 Chemistry Syllabus

    UNIT 7: EQUILIBRIUM

    Meaning of equilibrium, concept of dynamic equilibrium.

    JEE Main 2014 Chemistry Syllabus

    Equilibria involving physical processes: Solid -liquid, liquid – gas and solid – gas equilibria, Henry’s law, general characterics of equilibrium involving physical processes.

    Equilibria involving chemical processes: Law of chemical equilibrium, equilibrium constants (Kp and Kc) and their significance, significance of DG and DGo in chemical equilibria, factors affecting equilibrium concentration, pressure, temperature, effect of catalyst; Le Chatelier’s principle.

    JEE Main 2014 Chemistry Syllabus

    Ionic equilibrium: Weak and strong electrolytes, ionization of electrolytes, various concepts of acids and bases (Arrhenius, Br??nsted – Lowry and Lewis) and their ionization, acid – base equilibria (including multistage ionization) and ionization constants, ionization of water, pH scale, common ion effect, hydrolysis of salts and pH of their solutions, solubility of sparingly soluble salts and solubility products, buffer solutions.

    UNIT 8: REDOX REACTIONS AND ELECTROCHEMISTRY

    JEE Main 2014 Chemistry Syllabus

    Electronic concepts of oxidation and reduction, redox reactions, oxidation number, rules for assigning oxidation number, balancing of redox reactions.

    Eectrolytic and metallic conduction, conductance in electrolytic solutions, specific and molar conductivities and their variation with concentration: Kohlrausch’s law and its applications.

    Electrochemical cells – Electrolytic and Galvanic cells, different types of electrodes, electrode potentials including standard electrode potential, half – cell and cell reactions, emf of a Galvanic cell and its measurement; Nernst equation and its applications; Relationship between cell potential and Gibbs’ energy change; Dry cell and lead accumulator; Fuel cells.

    JEE Main 2014 Chemistry Syllabus

    UNIT 9 : CHEMICAL KINETICS

    Rate of a chemical reaction, factors affecting the rate of reactions: concentration, temperature, pressure and catalyst; elementary and complex reactions, order and molecularity of reactions, rate law, rate constant and its units, differential and integral forms of zero and first order reactions, their characteristics and half – lives, effect of temperature on rate of reactions – Arrhenius theory, activation energy and its calculation, collision theory of bimolecular gaseous reactions (no derivation).

    JEE Main 2014 Chemistry Syllabus

    UNIT-10 : SURFACE CHEMISTRY

    Adsorption- Physisorption and chemisorption and their characteristics, factors affecting adsorption of gases on solids – Freundlich and Langmuir adsorption isotherms, adsorption from solutions.

    Colloidal state – distinction among true solutions, colloids and suspensions, classification of colloids – lyophilic, lyophobic; multi molecular, macromolecular and associated colloids (micelles), preparation and properties of colloids – Tyndall effect, Brownian movement, electrophoresis, dialysis, coagulation and flocculation; Emulsions and their characteristics.


    SECTION – B





    JEE Main 2014 Chemistry Syllabus

    INORGANIC CHEMISTRY

    UNIT 11: CLASSIFICATON OF ELEMENTS AND PERIODICITY IN PROPERTIES

    Modem periodic law and present form of the periodic table, s, p, d and f block elements, periodic trends in properties of elements atomic and ionic radii, ionization enthalpy, electron gain enthalpy, valence, oxidation states and chemical reactivity.

    UNIT 12: GENERAL PRINCIPLES AND PROCESSES OF ISOLATION OF METALS

    JEE Main 2014 Chemistry Syllabus

    Modes of occurrence of elements in nature, minerals, ores; Steps involved in the extraction of metals – concentration, reduction (chemical and electrolytic methods) and refining with special reference to the extraction of Al, Cu, Zn and Fe; Thermodynamic and electrochemical principles involved in the extraction of metals.

    UNIT 13: HYDROGEN

    Position of hydrogen in periodic table, isotopes, preparation, properties and uses of hydrogen; Physical and chemical properties of water and heavy water; Structure, preparation, reactions and uses of hydrogen peroxide; Hydrogen as a fuel.

    JEE Main 2014 Chemistry Syllabus

    UNIT 14: S – BLOCK ELEMENTS (ALKALI AND ALKALINE EARTH METALS)

    Group – 1 and 2 Elements

    General introduction, electronic configuration and general trends in physical and chemical properties of elements, anomalous properties of the first element of each group, diagonal relationships.

    Preparation and properties of some important compounds – sodium carbonate and sodium hydroxide; Industrial uses of lime, limestone, Plaster of Paris and cement; Biological significance of Na, K, Mg and Ca.

    JEE Main 2014 Chemistry Syllabus

    UNIT 15: P – BLOCK ELEMENTS

    Group – 13 to Group 18 Elements

    General Introduction: Electronic configuration and general trends in physical and chemical properties of elements across the periods and down the groups; unique behaviour of the first element in each group.

    Groupwise study of the p – block elements

    Group – 13

    JEE Main 2014 Chemistry Syllabus

    Preparation, properties and uses of boron and aluminium; properties of boric acid, diborane, boron trifluoride, aluminium chloride and alums.

    Group – 14

    Allotropes of carbon, tendency for catenation; Structure & properties of silicates, and zeolites.

    Group – 15

    Properties and uses of nitrogen and phosphorus; Allotrophic forms of phosphorus; Preparation, properties, structure and uses of ammonia, nitric acid, phosphine and phosphorus halides, (PCl3, PCl5); Structures of oxides and oxoacids of phosphorus.

    JEE Main 2014 Chemistry Syllabus

    Group – 16

    Preparation, properties, structures and uses of ozone; Allotropic forms of sulphur; Preparation, properties, structures and uses of sulphuric acid (including its industrial preparation); Structures of oxoacids of sulphur.

    Group – 17

    Preparation, properties and uses of hydrochloric acid; Trends in the acidic nature of hydrogen halides; Structures of Interhalogen compounds and oxides and oxoacids of halogens.

    JEE Main 2014 Chemistry Syllabus

    Group –18

    Occurrence and uses of noble gases; Structures of fluorides and oxides of xenon.

    UNIT 16: d – and f – BLOCK ELEMENTS

    Transition Elements

    General introduction, electronic configuration, occurrence and characteristics, general trends in properties of the first row transition elements – physical properties, ionization enthalpy, oxidation states, atomic radii, colour, catalytic behaviour, magnetic properties, complex formation, interstitial compounds, alloy formation; Preparation, properties and uses of K2 Cr2 O7 and KMnO4 .

    JEE Main 2014 Chemistry Syllabus

    Inner Transition Elements

    Lanthanoids – Electronic configuration, oxidation states and lanthanoid contraction.

    Actinoids – Electronic configuration and oxidation states.

    UNIT 17: CO-ORDINATION COMPOUNDS

    Introduction to co-ordination compounds, Werner’s theory; ligands, co-ordination number, denticity, chelation; IUPAC nomenclature of mononuclear co-ordination compounds, isomerism; Bonding-Valence bond approach and basic ideas of Crystal field theory, colour and magnetic properties; Importance of co-ordination compounds (in qualitative analysis, extraction of metals and in biological systems).

    JEE Main 2014 Chemistry Syllabus

    UNIT 18: ENVIRONMENTAL CHEMISTRY

    Environmental pollution – Atmospheric, water and soil.

    Atmospheric pollution – Tropospheric and Stratospheric

    Tropospheric pollutants – Gaseous pollutants: Oxides of carbon, nitrogen and sulphur, hydrocarbons; their sources, harmful effects and prevention; Green house effect and Global warming; Acid rain;

    Particulate pollutants: Smoke, dust, smog, fumes, mist; their sources, harmful effects and prevention.

    JEE Main 2014 Chemistry Syllabus

    Stratospheric pollution- Formation and breakdown of ozone, depletion of ozone layer – its mechanism and effects.

    Water Pollution – Major pollutants such as, pathogens, organic wastes and chemical pollutants; their harmful effects and prevention.

    Soil pollution – Major pollutants such as: Pesticides (insecticides,. herbicides and fungicides), their harmful effects and prevention. Strategies to control environmental pollution.

    SECTION-C





    JEE Main 2014 Chemistry Syllabus

    ORGANIC CHEMISTRY

    UNIT 19: PURIFICATION AND CHARACTERISATION OF ORGANIC COMPOUNDS

    Purification – Crystallization, sublimation, distillation, differential extraction and chromatography – principles and their applications.

    Qualitative analysis – Detection of nitrogen, sulphur, phosphorus and halogens.

    Quantitative analysis (basic principles only) – Estimation of carbon, hydrogen, nitrogen, halogens, sulphur, phosphorus.

    JEE Main 2014 Chemistry Syllabus

    Calculations of empirical formulae and molecular formulae; Numerical problems in organic quantitative analysis.

    UNIT 20: SOME BASIC PRINCIPLES OF ORGANIC CHEMISTRY

    Tetravalency of carbon; Shapes of simple molecules – hybridization (s and p); Classification of organic compounds based on functional groups: – C = C – , – C h C – and those containing halogens, oxygen, nitrogen and sulphur; Homologous series; Isomerism – structural and stereoisomerism.

    JEE Main 2014 Chemistry Syllabus

    Nomenclature (Trivial and IUPAC)

    Covalent bond fission – Homolytic and heterolytic: free radicals, carbocations and carbanions; stability of carbocations and free radicals, electrophiles and nucleophiles.

    Electronic displacement in a covalent bond – Inductive effect, electromeric effect, resonance and hyperconjugation.

    JEE Main 2014 Chemistry Syllabus

    UNIT 21: HYDROCARBONS

    Classification, isomerism, IUPAC nomenclature, general methods of preparation, properties and reactions.

    Alkanes – Conformations: Sawhorse and Newman projections (of ethane); Mechanism of halogenation of alkanes.

    Alkenes – Geometrical isomerism; Mechanism of electrophilic addition: addition of hydrogen, halogens, water, hydrogen halides (Markownikoff’s and peroxide effect); Ozonolysis and polymerization.

    Alkynes – Acidic character; Addition of hydrogen, halogens, water and hydrogen halides; Polymerization.

    JEE Main 2014 Chemistry Syllabus

    Aromatic hydrocarbons – Nomenclature, benzene – structure and aromaticity; Mechanism of electrophilic substitution: halogenation, nitration, Friedel – Craft’s alkylation and acylation, directive influence of functional group in mono-substituted benzene.

    UNIT 22: ORGANIC COMPOUNDS CONTAINING HALOGENS

    General methods of preparation, properties and reactions; Nature of C-X bond; Mechanisms of substitution reactions.

    Uses; Environmental effects of chloroform & iodoform.

    JEE Main 2014 Chemistry Syllabus

    UNIT 23: ORGANIC COMPOUNDS CONTAINING OXYGEN

    General methods of preparation, properties, reactions and uses.

    ALCOHOLS, PHENOLS AND ETHERS

    Alcohols: Identification of primary, secondary and tertiary alcohols; mechanism of dehydration.

    Phenols: Acidic nature, electrophilic substitution reactions: halogenation, nitration and sulphonation, Reimer – Tiemann reaction.

    JEE Main 2014 Chemistry Syllabus

    Ethers: Structure.

    Aldehyde and Ketones: Nature of carbonyl group;Nucleophilic addition to >C=O group, relative reactivities of aldehydes and ketones; Important reactions such as – Nucleophilic addition reactions (addition of HCN, NH3 and its derivatives), Grignard reagent; oxidation; reduction (Wolff Kishner and Clemmensen); acidity of r – hydrogen, aldol condensation, Cannizzaro reaction, Haloform reaction; Chemical tests to distinguish between aldehydes and Ketones.

    JEE Main 2014 Chemistry Syllabus

    CARBOXYLIC ACIDS

    Acidic strength and factors affecting it.

    UNIT 24: ORGANIC COMPOUNDS CONTAINING NITROGEN

    General methods of preparation, properties, reactions and uses. Amines: Nomenclature, classification, structure, basic character and identification of primary, secondary and tertiary amines and their basic character. Diazonium Salts: Importance in synthetic organic chemistry.

    JEE Main 2014 Chemistry Syllabus

    UNIT 25: POLYMERS

    General introduction and classification of polymers, general methods of polymerization-addition and condensation, copolymerization; Natural and synthetic rubber and vulcanization; some important polymers with emphasis on their monomers and uses – polythene, nylon, polyester and bakelite.

    UNIT 26: BIOMOLECULES

    General introduction and importance of biomolecules. CARBOHYDRATES – Classification: aldoses and ketoses; monosaccharides (glucose and fructose) and constituent monosaccharides of oligosacchorides (sucrose, lactose and maltose).

    JEE Main 2014 Chemistry Syllabus

    PROTEINS – Elementary Idea of r – amino acids, peptide bond, polypeptides; Proteins: primary, secondary, tertiary and quaternary structure (qualitative idea only), denaturation of proteins, enzymes.

    VITAMINS – Classification and functions.

    NUCLEIC ACIDS – Chemical constitution of DNA and RNA. Biological functions of nucleic acids.

    JEE Main 2014 Chemistry Syllabus

    UNIT 27: CHEMISTRY IN EVERYDAY LIFE

    Chemicals in medicines – Analgesics, tranquilizers, antiseptics, disinfectants, antimicrobials, antifertility drugs, antibiotics, antacids, antihistamins – their meaning and common examples.

    Chemicals in food – Preservatives, artificial sweetening agents – common examples. Cleansing agents – Soaps and detergents, cleansing action.

    JEE Main 2014 Chemistry Syllabus

    UNIT 28: PRINCIPLES RELATED TO PRACTICAL CHEMISTRY

    Detection of extra elements (N,S, halogens) in organic compounds; Detection of the following functional groups: hydroxyl (alcoholic and phenolic), carbonyl (aldehyde and ketone), carboxyl and amino groups in organic compounds.

    Chemistry involved in the preparation of the following: Inorganic compounds: Mohr’s salt, potash alum. Organic compounds: Acetanilide, pnitroacetanilide, aniline yellow, iodoform.

    JEE Main 2014 Chemistry Syllabus

    Chemistry involved in the titrimetric excercises – Acids bases and the use of indicators, oxalic-acid vs KMnO4, Mohr’s salt vs KMnO4.

    Chemical principles involved in the qualitative salt analysis: Cations – Pb2+ , Cu2+, AI3+, Fe3+, Zn2+, Ni2+, Ca2+, Ba2+, Mg2+, NH4+. Anions- CO3 2-, S2-, SO4 2-, NO2-, NO3-, CI -, Br, I. (Insoluble salts excluded).

    JEE Main 2014 Chemistry Syllabus

    Chemical principles involved in the following experiments:

    1. Enthalpy of solution of CuSO4

    2. Enthalpy of neutralization of strong acid and strong base.

    3. Preparation of lyophilic and lyophobic sols.

    4. Kinetic study of reaction of iodide ion with hydrogen peroxide at room temperature

    Last edited by ajaytopgun; 18th June 2014 at 12:16 PM.

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