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At mention of the word conduction, we should immediately conjure up concepts of atomic and molecular activity because processes at these levels sustain this mode of heat transfer. Conduction may be viewed as the transfer of energy from the more energetic to the less energetic particles of a substance due to interactions between the particles. The physical mechanism of conduction is most easily explained by considering a gas and using ideas familiar from your thermodynamics background. Consider a gas in which a temperature gradient exists, and assume that there is no bulk, or macroscopic, motion. The gas may occupy the space between two surfaces that are maintained at different temperatures.We associate the temperature at any point with the energy of gas molecules in proximity to the point. This energy is related to the random translational motion, as well as to the internal rotational and vibrational motions, of the molecules.
Higher temperatures are associated with higher molecular energies. When neighboring molecules collide, as they are constantly doing, a transfer of energy from the more energetic to the less energetic molecules must occur. In the presence of a temperature gradient, energy transfer by conduction must then occur in the direction of decreasing temperature. This would be true even in the absence of collisions. The hypothetical plane at is constantly being crossed by molecules from above and below due to their random motion. However, molecules from above are associated with a higher temperature than those from below, in which case there must be a net transfer of energy in the positive x-direction. Collisions between molecules enhance this energy transfer. We may speak of the net transfer of energy by random molecular motion as a diffusion of energy.